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Gold is
a chemical element with the symbol Au (from the Latin aurum) and atomic number
79. It is a highly sought-after precious metal which, for many centuries, has
been used as money, a store of value and in jewelery. The metal occurs as nuggets
or grains in rocks, underground "veins" and
in alluvial deposits. It is one of the coinage metals. Gold is dense, soft,
shiny and the most malleable and ductile of the known metals. Pure gold has
an attractive bright yellow colour and is one of only two coloured metal elements,
the other being copper. All other metals are silver or grey.
Gold forms the basis for a monetary standard used by the International Monetary
Fund (IMF) and the Bank for International Settlements (BIS). The ISO currency
code of gold bullion is XAU. Modern industrial uses include dentistry and electronics,
where gold has traditionally found use because of its good resistance to oxidative
corrosion.
Chemically, gold is a trivalent and univalent transition metal. Gold does
not react with most chemicals, but is attacked by chlorine, fluorine, aqua
regia and cyanide. Gold dissolves in mercury, forming amalgam alloys, but does
not react with it. Gold is insoluble in nitric acid, which will dissolve silver
and base metals, and this is the basis of the gold refining technique known
as "inquartation and parting". Nitric acid has long been used to
confirm the presence of gold in items, and this is the origin of the colloquial
term "acid test," referring to a gold standard test for genuine value.
interesting
Gold Compounds
The most common gold compounds are auric chloride (AuCl3) and chlorauric acid
(HAuCl4). A mixture of one part nitric acid with three of hydrochloric acid
is called aqua regia (because it dissolved gold, the King of Metals). It is
unaffected by air and most reagents. It is found free in nature and associated
with quartz, pyrite and other minerals. Two thirds of the world's supply comes
from South Africa, and 2/3 of USA production is from South Dakota and Nevada.
Gold is found in sea water, but no effective economic process has been designed
(yet) to extract it from this source.
Common reference compound: no defined reference.
Isotope 1 Isotope
2 Isotope 3
Isotope 197Au
Natural abundance /% 100
Spin (I) 3/2
Frequency relative to 1H = 100 (MHz) 1.754000 Receptivity, DC, relative to 13C = 1.00 0.158
Magnetogyric ratio, γ (107 rad T-1 s-1) 0.473060
Magnetic moment, μ (μN) 0.191271
Nuclear quadrupole moment, Q (barn) 0.547
Line width factor, 1056l (m4) 0.29
Common reference compound: no defined reference.
Isotope 1 Isotope 2 Isotope
3
Isotope 197Au
Natural abundance /% 100
Spin (I) 3/2
Frequency relative to 1H = 100 (MHz) 1.754000
Receptivity, DP, relative to 1H = 1.00 0.0000277
Receptivity, DC, relative to 13C = 1.00 0.158
Magnetogyric ratio, γ (107 rad T-1 s-1) 0.473060
Magnetic moment, μ (μN) 0.191271
Nuclear quadrupole moment, Q (barn) 0.547
Line width factor, 1056l (m4) 0.29
Temperatures
Melting point
[/K]: 1337.33 [or 1064.18 °C (1947.52 °F)]
Boiling point
[/K]: 3129 [or 2856 °C (5173 °F)] (liquid range: 1791.67 K)
General
Name, Symbol, Number gold, Au, 79
Chemical series transition metals
Group, Period, Block 11, 6, d
Appearance metallic yellow
Standard atomic weight 196.966569(4) g·mol−1
Electron configuration [Xe] 4f14 5d10 6s1
Electrons per shell 2, 8, 18, 32, 18, 1
Physical properties
Phase solid
Density (near r.t.) 19.3 g·cm−3
Liquid density at m.p. 17.31 g·cm−3
Melting point 1337.33 K
(1064.18 °C, 1947.52 °F)
Boiling point 3129 K
(2856 °C, 5173 °F)
Heat of fusion 12.55 kJ·mol−1
Heat of vaporization 324 kJ·mol−1
Heat capacity (25 °C) 25.418 J·mol−1·K−1
Vapor pressure P(Pa) 1 10 100 1 k 10 k 100 k
at T(K) 1646 1814 2021 2281 2620 3078
Atomic properties
Crystal structure cubic face centered
Oxidation states −1, 1, 2, 3, 4, 5, 6, 7
(amphoteric oxide)
Electronegativity 2.54 (Pauling scale)
Ionization energies 1st: 890.1 kJ/mol
2nd: 1980 kJ/mol
Atomic radius 135 pm
Atomic radius (calc.) 174 pm
Covalent radius 144 pm
Van der Waals radius 166 pm
Miscellaneous
Magnetic ordering no data
Electrical resistivity (20 °C) 22.14 n Ω·m
Thermal conductivity (300 K) 318 W·m−1·K−1
Thermal expansion (25 °C) 14.2 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (hard-drawn)
2030 m·s−1
Young's modulus 78 GPa
Shear modulus 27 GPa
Bulk modulus 220 GPa
Poisson ratio 0.44
Mohs hardness 2.5
Vickers hardness 216 MPa
Brinell hardness ? 2450 MPa
CAS registry number 7440-57-5
Selected isotopes
Main article: Isotopes of gold iso NA half-life DM DE (MeV) DP
195Au syn 186.10 d ε 0.227 195Pt
196Au syn 6.183 d ε 1.506 196Pt
β- 0.686 196Hg
197Au 100% Au is stable with 118 neutrons
198Au syn 2.69517 d β- 1.372 198Hg
199Au syn 3.169 d β- 0.453 199Hg
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